AustralieFrV1, Main, Exploration, bibRecord, 003D46

Pressure‐Induced Intersite BiM (M=Ru, Ir) Valence Transitions in Hexagonal Perovskites

Identifieur interne : 003D46 ( Main/Exploration ); précédent : 003D45; suivant : 003D47

Pressure‐Induced Intersite BiM (M=Ru, Ir) Valence Transitions in Hexagonal Perovskites

Auteurs : Zixin Huang [Australie] ; Josie E. Auckett [Australie] ; Peter E. R. Blanchard [Australie] ; Brendan J. Kennedy [Australie] ; Wojciech Miiller [Australie] ; Qingdi Zhou [Australie] ; Maxim Avdeev [Australie] ; Mark R. Johnson [France] ; Mohamed Zbiri [France] ; Gaston Garbarino [France] ; William G. Marshall [Royaume-Uni] ; Qinfen Gu [Australie] ; Chris D. Ling [Australie]

Source :

Angewandte Chemie [ 0044-8249 ] ; 2014-03-24.

RBID : ISTEX:1A5F1FF71EBDA727A4C55CFE52303827449E80C3

Abstract

Pressure‐induced charge transfer from Bi to Ir/Ru is observed in the hexagonal perovskites Ba3+nBiM2+nO9+3n (n=0,1; M=Ir,Ru). These compounds show first‐order, circa 1 % volume contractions at room temperature above 5 GPa, which are due to the large reduction in the effective ionic radius of Bi when the 6s shell is emptied on oxidation, compared to the relatively negligible effect of reduction on the radii of Ir or Ru. They are the first such transitions involving 4d and 5d compounds, and they double the total number of cases known. Ab initio calculations suggest that magnetic interactions through very short (ca. 2.6 Å) MM bonds contribute to the finely balanced nature of their electronic states.

Url:

https://api.istex.fr/document/1A5F1FF71EBDA727A4C55CFE52303827449E80C3/fulltext/pdf

DOI: 10.1002/ange.201311159

Affiliations:

Links toward previous steps (curation, corpus...)

to stream Istex, to step Corpus: 000502
to stream Istex, to step Curation: 000502
to stream Istex, to step Checkpoint: 000070
to stream Main, to step Merge: 003D97
to stream Main, to step Curation: 003D46

Le document en format XML

<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">Pressure‐Induced Intersite BiM (M=Ru, Ir) Valence Transitions in Hexagonal Perovskites</title>
<author><name sortKey="Huang, Zixin" sort="Huang, Zixin" uniqKey="Huang Z" first="Zixin" last="Huang">Zixin Huang</name>
</author>
<author><name sortKey="Auckett, Josie E" sort="Auckett, Josie E" uniqKey="Auckett J" first="Josie E." last="Auckett">Josie E. Auckett</name>
</author>
<author><name sortKey="Blanchard, Peter E R" sort="Blanchard, Peter E R" uniqKey="Blanchard P" first="Peter E. R." last="Blanchard">Peter E. R. Blanchard</name>
</author>
<author><name sortKey="Kennedy, Brendan J" sort="Kennedy, Brendan J" uniqKey="Kennedy B" first="Brendan J." last="Kennedy">Brendan J. Kennedy</name>
</author>
<author><name sortKey="Miiller, Wojciech" sort="Miiller, Wojciech" uniqKey="Miiller W" first="Wojciech" last="Miiller">Wojciech Miiller</name>
</author>
<author><name sortKey="Zhou, Qingdi" sort="Zhou, Qingdi" uniqKey="Zhou Q" first="Qingdi" last="Zhou">Qingdi Zhou</name>
</author>
<author><name sortKey="Avdeev, Maxim" sort="Avdeev, Maxim" uniqKey="Avdeev M" first="Maxim" last="Avdeev">Maxim Avdeev</name>
</author>
<author><name sortKey="Johnson, Mark R" sort="Johnson, Mark R" uniqKey="Johnson M" first="Mark R." last="Johnson">Mark R. Johnson</name>
</author>
<author><name sortKey="Zbiri, Mohamed" sort="Zbiri, Mohamed" uniqKey="Zbiri M" first="Mohamed" last="Zbiri">Mohamed Zbiri</name>
</author>
<author><name sortKey="Garbarino, Gaston" sort="Garbarino, Gaston" uniqKey="Garbarino G" first="Gaston" last="Garbarino">Gaston Garbarino</name>
</author>
<author><name sortKey="Marshall, William G" sort="Marshall, William G" uniqKey="Marshall W" first="William G." last="Marshall">William G. Marshall</name>
</author>
<author><name sortKey="Gu, Qinfen" sort="Gu, Qinfen" uniqKey="Gu Q" first="Qinfen" last="Gu">Qinfen Gu</name>
</author>
<author><name sortKey="Ling, Chris D" sort="Ling, Chris D" uniqKey="Ling C" first="Chris D." last="Ling">Chris D. Ling</name>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">ISTEX</idno>
<idno type="RBID">ISTEX:1A5F1FF71EBDA727A4C55CFE52303827449E80C3</idno>
<date when="2014" year="2014">2014</date>
<idno type="doi">10.1002/ange.201311159</idno>
<idno type="url">https://api.istex.fr/document/1A5F1FF71EBDA727A4C55CFE52303827449E80C3/fulltext/pdf</idno>
<idno type="wicri:Area/Istex/Corpus">000502</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">000502</idno>
<idno type="wicri:Area/Istex/Curation">000502</idno>
<idno type="wicri:Area/Istex/Checkpoint">000070</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Checkpoint">000070</idno>
<idno type="wicri:doubleKey">0044-8249:2014:Huang Z:pressure:induced:intersite</idno>
<idno type="wicri:Area/Main/Merge">003D97</idno>
<idno type="wicri:Area/Main/Curation">003D46</idno>
<idno type="wicri:Area/Main/Exploration">003D46</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">Pressure‐Induced Intersite BiM (M=Ru, Ir) Valence Transitions in Hexagonal Perovskites<ref type="note" target="#nss"></ref>
</title>
<author><name sortKey="Huang, Zixin" sort="Huang, Zixin" uniqKey="Huang Z" first="Zixin" last="Huang">Zixin Huang</name>
<affiliation wicri:level="4"><country xml:lang="fr">Australie</country>
<wicri:regionArea>School of Chemistry, The University of Sydney</wicri:regionArea>
<placeName><settlement type="city">Sydney</settlement>
<region type="état">Nouvelle-Galles du Sud</region>
</placeName>
<orgName type="university">Université de Sydney</orgName>
</affiliation>
</author>
<author><name sortKey="Auckett, Josie E" sort="Auckett, Josie E" uniqKey="Auckett J" first="Josie E." last="Auckett">Josie E. Auckett</name>
<affiliation wicri:level="4"><country xml:lang="fr">Australie</country>
<wicri:regionArea>School of Chemistry, The University of Sydney</wicri:regionArea>
<placeName><settlement type="city">Sydney</settlement>
<region type="état">Nouvelle-Galles du Sud</region>
</placeName>
<orgName type="university">Université de Sydney</orgName>
</affiliation>
</author>
<author><name sortKey="Blanchard, Peter E R" sort="Blanchard, Peter E R" uniqKey="Blanchard P" first="Peter E. R." last="Blanchard">Peter E. R. Blanchard</name>
<affiliation wicri:level="4"><country xml:lang="fr">Australie</country>
<wicri:regionArea>School of Chemistry, The University of Sydney</wicri:regionArea>
<placeName><settlement type="city">Sydney</settlement>
<region type="état">Nouvelle-Galles du Sud</region>
</placeName>
<orgName type="university">Université de Sydney</orgName>
</affiliation>
</author>
<author><name sortKey="Kennedy, Brendan J" sort="Kennedy, Brendan J" uniqKey="Kennedy B" first="Brendan J." last="Kennedy">Brendan J. Kennedy</name>
<affiliation wicri:level="4"><country xml:lang="fr">Australie</country>
<wicri:regionArea>School of Chemistry, The University of Sydney</wicri:regionArea>
<placeName><settlement type="city">Sydney</settlement>
<region type="état">Nouvelle-Galles du Sud</region>
</placeName>
<orgName type="university">Université de Sydney</orgName>
</affiliation>
</author>
<author><name sortKey="Miiller, Wojciech" sort="Miiller, Wojciech" uniqKey="Miiller W" first="Wojciech" last="Miiller">Wojciech Miiller</name>
<affiliation wicri:level="4"><country xml:lang="fr">Australie</country>
<wicri:regionArea>School of Chemistry, The University of Sydney</wicri:regionArea>
<placeName><settlement type="city">Sydney</settlement>
<region type="état">Nouvelle-Galles du Sud</region>
</placeName>
<orgName type="university">Université de Sydney</orgName>
</affiliation>
</author>
<author><name sortKey="Zhou, Qingdi" sort="Zhou, Qingdi" uniqKey="Zhou Q" first="Qingdi" last="Zhou">Qingdi Zhou</name>
<affiliation wicri:level="4"><country xml:lang="fr">Australie</country>
<wicri:regionArea>School of Chemistry, The University of Sydney</wicri:regionArea>
<placeName><settlement type="city">Sydney</settlement>
<region type="état">Nouvelle-Galles du Sud</region>
</placeName>
<orgName type="university">Université de Sydney</orgName>
</affiliation>
</author>
<author><name sortKey="Avdeev, Maxim" sort="Avdeev, Maxim" uniqKey="Avdeev M" first="Maxim" last="Avdeev">Maxim Avdeev</name>
<affiliation wicri:level="1"><country xml:lang="fr">Australie</country>
<wicri:regionArea>Bragg Institute, ANSTO</wicri:regionArea>
<wicri:noRegion>ANSTO</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Johnson, Mark R" sort="Johnson, Mark R" uniqKey="Johnson M" first="Mark R." last="Johnson">Mark R. Johnson</name>
<affiliation wicri:level="1"><country xml:lang="fr">France</country>
<wicri:regionArea>Institut Laue‐Langevin, BP 156</wicri:regionArea>
<wicri:noRegion>BP 156</wicri:noRegion>
<wicri:noRegion>BP 156</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Zbiri, Mohamed" sort="Zbiri, Mohamed" uniqKey="Zbiri M" first="Mohamed" last="Zbiri">Mohamed Zbiri</name>
<affiliation wicri:level="1"><country xml:lang="fr">France</country>
<wicri:regionArea>Institut Laue‐Langevin, BP 156</wicri:regionArea>
<wicri:noRegion>BP 156</wicri:noRegion>
<wicri:noRegion>BP 156</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Garbarino, Gaston" sort="Garbarino, Gaston" uniqKey="Garbarino G" first="Gaston" last="Garbarino">Gaston Garbarino</name>
<affiliation wicri:level="1"><country xml:lang="fr">France</country>
<wicri:regionArea>European Synchrotron Research Facility, BP 220</wicri:regionArea>
<wicri:noRegion>BP 220</wicri:noRegion>
<wicri:noRegion>BP 220</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Marshall, William G" sort="Marshall, William G" uniqKey="Marshall W" first="William G." last="Marshall">William G. Marshall</name>
<affiliation wicri:level="1"><country xml:lang="fr">Royaume-Uni</country>
<wicri:regionArea>ISIS Facility, STFC, Rutherford Appleton Laboratory</wicri:regionArea>
<wicri:noRegion>Rutherford Appleton Laboratory</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Gu, Qinfen" sort="Gu, Qinfen" uniqKey="Gu Q" first="Qinfen" last="Gu">Qinfen Gu</name>
<affiliation wicri:level="1"><country xml:lang="fr">Australie</country>
<wicri:regionArea>Australian Synchrotron, 800 Blackburn Road</wicri:regionArea>
<wicri:noRegion>800 Blackburn Road</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Ling, Chris D" sort="Ling, Chris D" uniqKey="Ling C" first="Chris D." last="Ling">Chris D. Ling</name>
<affiliation wicri:level="4"><country xml:lang="fr">Australie</country>
<wicri:regionArea>School of Chemistry, The University of Sydney</wicri:regionArea>
<placeName><settlement type="city">Sydney</settlement>
<region type="état">Nouvelle-Galles du Sud</region>
</placeName>
<orgName type="university">Université de Sydney</orgName>
</affiliation>
<affiliation wicri:level="1"><country wicri:rule="url">Australie</country>
</affiliation>
<affiliation wicri:level="4"><country xml:lang="fr">Australie</country>
<wicri:regionArea>Correspondence address: School of Chemistry, The University of Sydney</wicri:regionArea>
<placeName><settlement type="city">Sydney</settlement>
<region type="état">Nouvelle-Galles du Sud</region>
</placeName>
<orgName type="university">Université de Sydney</orgName>
</affiliation>
</author>
</analytic>
<monogr></monogr>
<series><title level="j" type="main">Angewandte Chemie</title>
<title level="j" type="alt">ANGEWANDTE CHEMIE</title>
<idno type="ISSN">0044-8249</idno>
<idno type="eISSN">1521-3757</idno>
<imprint><biblScope unit="vol">126</biblScope>
<biblScope unit="issue">13</biblScope>
<biblScope unit="page" from="3482">3482</biblScope>
<biblScope unit="page" to="3485">3485</biblScope>
<biblScope unit="page-count">4</biblScope>
<publisher>WILEY‐VCH Verlag</publisher>
<pubPlace>Weinheim</pubPlace>
<date type="published" when="2014-03-24">2014-03-24</date>
</imprint>
<idno type="ISSN">0044-8249</idno>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><idno type="ISSN">0044-8249</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass></textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">Pressure‐induced charge transfer from Bi to Ir/Ru is observed in the hexagonal perovskites Ba3+nBiM2+nO9+3n (n=0,1; M=Ir,Ru). These compounds show first‐order, circa 1 % volume contractions at room temperature above 5 GPa, which are due to the large reduction in the effective ionic radius of Bi when the 6s shell is emptied on oxidation, compared to the relatively negligible effect of reduction on the radii of Ir or Ru. They are the first such transitions involving 4d and 5d compounds, and they double the total number of cases known. Ab initio calculations suggest that magnetic interactions through very short (ca. 2.6 Å) MM bonds contribute to the finely balanced nature of their electronic states.</div>
</front>
</TEI>
<affiliations><list><country><li>Australie</li>
<li>France</li>
<li>Royaume-Uni</li>
</country>
<region><li>Nouvelle-Galles du Sud</li>
</region>
<settlement><li>Sydney</li>
</settlement>
<orgName><li>Université de Sydney</li>
</orgName>
</list>
<tree><country name="Australie"><region name="Nouvelle-Galles du Sud"><name sortKey="Huang, Zixin" sort="Huang, Zixin" uniqKey="Huang Z" first="Zixin" last="Huang">Zixin Huang</name>
</region>
<name sortKey="Auckett, Josie E" sort="Auckett, Josie E" uniqKey="Auckett J" first="Josie E." last="Auckett">Josie E. Auckett</name>
<name sortKey="Avdeev, Maxim" sort="Avdeev, Maxim" uniqKey="Avdeev M" first="Maxim" last="Avdeev">Maxim Avdeev</name>
<name sortKey="Blanchard, Peter E R" sort="Blanchard, Peter E R" uniqKey="Blanchard P" first="Peter E. R." last="Blanchard">Peter E. R. Blanchard</name>
<name sortKey="Gu, Qinfen" sort="Gu, Qinfen" uniqKey="Gu Q" first="Qinfen" last="Gu">Qinfen Gu</name>
<name sortKey="Kennedy, Brendan J" sort="Kennedy, Brendan J" uniqKey="Kennedy B" first="Brendan J." last="Kennedy">Brendan J. Kennedy</name>
<name sortKey="Ling, Chris D" sort="Ling, Chris D" uniqKey="Ling C" first="Chris D." last="Ling">Chris D. Ling</name>
<name sortKey="Ling, Chris D" sort="Ling, Chris D" uniqKey="Ling C" first="Chris D." last="Ling">Chris D. Ling</name>
<name sortKey="Ling, Chris D" sort="Ling, Chris D" uniqKey="Ling C" first="Chris D." last="Ling">Chris D. Ling</name>
<name sortKey="Miiller, Wojciech" sort="Miiller, Wojciech" uniqKey="Miiller W" first="Wojciech" last="Miiller">Wojciech Miiller</name>
<name sortKey="Zhou, Qingdi" sort="Zhou, Qingdi" uniqKey="Zhou Q" first="Qingdi" last="Zhou">Qingdi Zhou</name>
</country>
<country name="France"><noRegion><name sortKey="Johnson, Mark R" sort="Johnson, Mark R" uniqKey="Johnson M" first="Mark R." last="Johnson">Mark R. Johnson</name>
</noRegion>
<name sortKey="Garbarino, Gaston" sort="Garbarino, Gaston" uniqKey="Garbarino G" first="Gaston" last="Garbarino">Gaston Garbarino</name>
<name sortKey="Zbiri, Mohamed" sort="Zbiri, Mohamed" uniqKey="Zbiri M" first="Mohamed" last="Zbiri">Mohamed Zbiri</name>
</country>
<country name="Royaume-Uni"><noRegion><name sortKey="Marshall, William G" sort="Marshall, William G" uniqKey="Marshall W" first="William G." last="Marshall">William G. Marshall</name>
</noRegion>
</country>
</tree>
</affiliations>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Wicri/Asie/explor/AustralieFrV1/Data/Main/Exploration

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 003D46 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 003D46 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Wicri/Asie
   |area=    AustralieFrV1
   |flux=    Main
   |étape=   Exploration
   |type=    RBID
   |clé=     ISTEX:1A5F1FF71EBDA727A4C55CFE52303827449E80C3
   |texte=   Pressure‐Induced Intersite BiM (M=Ru, Ir) Valence Transitions in Hexagonal Perovskites
}}

This area was generated with Dilib version V0.6.33.
Data generation: Tue Dec 5 10:43:12 2017. Site generation: Tue Mar 5 14:07:20 2024

	Serveur d'exploration sur les relations entre la France et l'Australie
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration sur les relations entre la France et l'Australie

Pressure‐Induced Intersite BiM (M=Ru, Ir) Valence Transitions in Hexagonal Perovskites

Pressure‐Induced Intersite BiM (M=Ru, Ir) Valence Transitions in Hexagonal Perovskites

Source :

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri